Why An exclusive NOR is an exclusive OR followed by an inverter, so it is an equality detector: the output is 1 when the two inputs match (0,0 or 1,1) and 0 when they differ. With two inputs, "they differ" means exactly one input is 1, so that condition drives the output low.
Watch out The choice saying a 1 appears when one and only one input is 1 describes the plain exclusive OR, which is the XNOR's complement. The choices about all inputs 0 or all inputs 1 describe NOR and AND behavior.
XNOR = "same" detector: match gives 1, mismatch gives 0. The NOR in the name means invert the XOR answer.