Why is skip propagation via the F2 region longer than that via the other ionospheric regions?
Why Single-hop distance is set by geometry: the higher the reflecting layer, the shallower the angle at which a ray can still be bent back and the farther it lands. The F2 region sits roughly 250 to 400 km up, well above the E region near 100 km, so one F2 hop can span about 2500 miles while an E-region hop is limited to roughly 1200 miles.
Watch out F2 is indeed the most heavily ionized region, but that high electron density is what raises the MUF, not what stretches the hop; the extra distance comes purely from the layer's altitude.
Highest mirror, longest bounce: F2 at ~250+ km gives ~2500 miles per hop, E at ~100 km only ~1200.