Why When a radio wave enters the ionized plasma of the ionosphere, the Earth's magnetic field makes the medium birefringent: the wave splits into two components, called the ordinary (o) and extraordinary (x) waves. Each is elliptically polarized and rotates in the opposite sense, and each sees a different refractive index, so they refract, absorb, and travel slightly differently and arrive independently. Their recombination at the receiver with varying phase is one cause of polarization fading. This effect is called magnetoionic splitting.
Watch out The name tempts people into thinking "extraordinary" means an unusual or rare long-skip path, but the term is purely a plasma physics label for one of the two magnetoionic modes, not a description of distance.
Ordinary/extraordinary = one wave split in two by Earth's magnetic field, both elliptically polarized.