Why Long-path signals take the longer great-circle route around the Earth, often 25,000 miles or more, so the band has to support many low-loss hops (or chordal hops) along a path where much of the ionosphere is in darkness. The 20 meter band is the classic long-path band, especially near sunrise and sunset along the grey line, with 40 meters working at night when absorption drops. These bands sit in the sweet spot: high enough to escape heavy D-layer absorption, low enough that the MUF supports the whole path.
Watch out 160 and 80 meters suffer too much absorption and noise to survive a trip most of the way around the world, and 10 and 6 meters would require a very high MUF sustained over the entire enormous path, which is rare.
Long path lives on 20 (with 40 at night); think grey-line DX on 14 MHz.